Photolysis of the dithiolactone 4-isopropylidene-3,3-dimethyl-1-thietan-2-thione; a Norrish type I reaction

Muthuramu, K and Ramamurthy, V (1980) Photolysis of the dithiolactone 4-isopropylidene-3,3-dimethyl-1-thietan-2-thione; a Norrish type I reaction. In: Journal of the Chemical Society, Chemical Communications (5). pp. 243-244.

PDF fulltext.pdf - Published Version Restricted to Registered users only Download (201kB) | Request a copy

Abstract

The dithiolactone (1) upon excitation gives the dithione (2) in cyclohexane and other aprotic solvents and a 1 : 1 adduct in hydroxylic solvents from an n* excited singlet state via an -cleavage process.

Item Type:	Journal Article
Publication:	Journal of the Chemical Society, Chemical Communications
Publisher:	Royal Society of Chemistry
Additional Information:	Copyright of this article belongs to Royal Society of Chemistry, 2009
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	08 Feb 2010 12:19
Last Modified:	19 Sep 2010 05:43
URI:	http://eprints.iisc.ac.in/id/eprint/22924

Actions (login required)

View Item