Dielectric Relaxation in SrLiB9O15 Glasses

Vaish, Rahul and Varma, KBR (2009) Dielectric Relaxation in SrLiB9O15 Glasses. In: Journal of the Electrochemical Society, 156 (3). G17-G21.

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Abstract

Transparent SrLiB9O15 (SLBO) glasses were fabricated via the conventional melt-quenching technique. X-ray powder diffraction and differential thermal analysis carried out on the as-quenched samples confirmed their amorphous and glassy nature, respectively. The dielectric constants in the 100 Hz to 10 MHz frequency range for SLBO glasses were measured as a function of temperature (300–1023 K). The dielectric relaxation characteristics were rationalized using the electric modulus formalism. The electrode polarization effect was subtracted from the low-frequency dielectric constant to have an insight into the intrinsic dielectric behavior of SLBO glasses. The imaginary part of electric modulus spectra was modeled using an approximate solution of Kohlrausch–Williams–Watts relation. The dielectric constant for the as-quenched glass increased with increasing temperature and exhibited anomalies in the vicinity of the glass transition and crystallization temperatures.

Item Type:	Journal Article
Publication:	Journal of the Electrochemical Society
Publisher:	The Electrochemical Society
Additional Information:	Copyright of this article belongs to The Electrochemical Society.
Department/Centre:	Division of Chemical Sciences > Materials Research Centre
Date Deposited:	03 Jul 2009 06:42
Last Modified:	19 Sep 2010 05:33
URI:	http://eprints.iisc.ac.in/id/eprint/20552

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