Total synthesis of the putative structure of the novel triquinane based sesquiterpenoid natural product dichomitol

Mehta, Goverdhan and Pallavi, Kotapalli (2006) Total synthesis of the putative structure of the novel triquinane based sesquiterpenoid natural product dichomitol. In: Tetrahedron Letters, 47 (47). pp. 8355-8360.

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Abstract

A total synthesis of the recently reported triquinane natural product dichomitol, isolated from the fermentation broth of Dichomitus squalens, has been accomplished from the commercially available 1,5-cyclooctadiene through a series of unambiguous synthetic steps. A complete mismatch between the spectral characteristics of the synthetic product and that of the natural product warrants a revision of the structure of dichomitol.

Item Type:	Journal Article
Publication:	Tetrahedron Letters
Publisher:	Elsavier
Additional Information:	Copyright of this article belongs to Elsavier.
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	13 Apr 2009 06:50
Last Modified:	19 Sep 2010 04:58
URI:	http://eprints.iisc.ac.in/id/eprint/17890

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