Reddy, Pattubala AN and Nethaji, Munirathinam and Chakravarty, Akhil R (2003) Supramolecular self assembly of a monomeric copper(II) complex of N-salicylidene-2-methoxyaniline forming three-dimensional closed and open channels. In: Inorganic Chemistry Communications, 6 (6). pp. 698-701.
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Abstract
A binary copper(II) complex [CuL2] (1), where HL is the Schiff base N-salicylidene-2-methoxyaniline, was prepared and structurally characterized. The complex which crystallizes in cubic space group Ia-3d with an unit cell dimension of 31.2451(17) , V = 30503(3) Angstrom(3), Z = 48, and refined to R-value of 0.0379 for 1700 data with I > 2sigma(I), shows a distorted four coordinate structure with a CuN2O2 chromophore. The complex self-assembles into a supramolecular architecture by non-covalent C-H...O interactions forming open and closed channels.
Item Type: | Journal Article |
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Publication: | Inorganic Chemistry Communications |
Publisher: | Elsevier Science B.V |
Additional Information: | Copyright of this article belongs to Elsevier Science B.V. |
Keywords: | copper(II) complex;Schiff base;X-ray structure;supramolecular architecture;lattice channels. |
Department/Centre: | Division of Chemical Sciences > Inorganic & Physical Chemistry |
Date Deposited: | 26 Nov 2009 08:02 |
Last Modified: | 19 Sep 2010 04:56 |
URI: | http://eprints.iisc.ac.in/id/eprint/17393 |
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