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Metal Nanowires and Intercalated Metal Layers in Single-Walled Carbon Nanotube Bundles

Govindaraj, A and Satishkumar, BC and Nath, Manashi and Rao, CNR (2000) Metal Nanowires and Intercalated Metal Layers in Single-Walled Carbon Nanotube Bundles. In: Chemistry of Materials, 12 (1). pp. 202-205.

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Abstract

Nanowires of Au, Ag, Pt, and Pd (1.0-1.4 nm diam) have been produced in the capillaries of single-walled carbon nanotubes (SWNTs). The nanowire is single-crystalline in some cases. Dispersions of the nanowires in alcohol show longitudinal plasmon absorption bands at different wavelengths, suggesting the presence of a distribution of aspect ratios. A novel phenomenon involving the intercalation of metal layers $(\sim 0.5 nm$ thick) in the intertubular space of SWNT bundles has been observed. SWNTs decorated by metal nanoparticles are formed in some of the preparations.

Item Type: Journal Article
Publication: Chemistry of Materials
Publisher: American Chemical Society
Additional Information: Copyright of this article belongs to American Chemical Society.
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 22 Oct 2008 10:47
Last Modified: 19 Sep 2010 04:51
URI: http://eprints.iisc.ac.in/id/eprint/16255

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