Investigations on $C_{70}H_{30}$ obtained by the Birch reduction of $C_{70}$

Govindaraj, A and Rathna, A and Chandrasekhar, J and Rao, CNR (1993) Investigations on $C_{70}H_{30}$ obtained by the Birch reduction of $C_{70}$. In: Proceedings of Indian Academy of Sciences: Chemical Sciences, 105 (4-5). pp. 303-309.

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Abstract

Upon Birch reduction, $C_{70}$ forms $C_{70}H_{30}$ as a major product. Besides reporting spectroscopic properties, we discuss the possible structures of $C_{70}H_{30}$ and suggest that the most stable structure is derived by exclusive 1,4-addition to the corannulene units and to the central pentaphenyl belt in $C_{70}$.

Item Type:	Journal Article
Publication:	Proceedings of Indian Academy of Sciences: Chemical Sciences
Publisher:	Indian Academy of Sciences
Additional Information:	Copyright of this article belongs to Indian Academy of Sciences.
Keywords:	Fullerene;Birch reduction;C30;C70H30;MNDO.
Department/Centre:	Division of Chemical Sciences > Solid State & Structural Chemistry Unit Division of Chemical Sciences > Organic Chemistry
Date Deposited:	16 Jul 2008
Last Modified:	19 Sep 2010 04:47
URI:	http://eprints.iisc.ac.in/id/eprint/14886

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