The first enantiospecific synthesis of (+)-10,11-epoxythapsan-10-ol: revision of the absolute stereochemistry of thapsanes

Srikrishna, A and Anebouselvy, K (2002) The first enantiospecific synthesis of (+)-10,11-epoxythapsan-10-ol: revision of the absolute stereochemistry of thapsanes. In: Tetrahedron-Letters, 43 (30). pp. 5261-5264.

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Abstract

The first enantiospecific synthesis of (+)-cis,anti,cis-1,8,12,12-tetramethyl-4-oxatricyclo[6.4.0.02,6]dodecan-3-ol (+)-1g, an enantiomer of natural thapsane isolated from Thapsia villosa var minor, is accomplished starting from (R)-carvone, which revises the absolute stereochemistry of natural thapsanes.

Item Type:	Journal Article
Publication:	Tetrahedron-Letters
Publisher:	Elsevier Science Ltd.
Additional Information:	Copyright of this article belongs to Elsevier Science Ltd.
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	27 Dec 2007
Last Modified:	19 Sep 2010 04:41
URI:	http://eprints.iisc.ac.in/id/eprint/12582

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