Rao, Ranga G and Sarma, DD (1990) Systematics in the 0 1s core-level spectra in transition metal oxides, $LaMO_3$ (M=V, Cr, Mn, Fe, Co and Ni). In: Modern Physics Letters B, 4 (4). pp. 277-282.
Full text not available from this repository. (Request a copy)Abstract
The O 1s core level spectra of transition metal oxides, $LaMO_3 $ (M=V, Cr, Mn, Fe, Co and Ni) show three features. The main peak always appears between 528 and 530 eV and is attributed to the well-screened oxygen $1s^1$ $2p^0$ hole configuration in every case. The poorly-screened feature ($1s^1$ $2p^0$ hole configuration) is found as a broad peak centred approximately 13 eV above the main peak. Another feature is at about 531 eV; the intensity of this peak is found to increase systematically across the series and its intensity cannot be explained in terms of carbonate impurity contamination. It is suggested that a considerable part of this 531 eV feature has an intrinsic origin.
| Item Type: | Journal Article |
|---|---|
| Publication: | Modern Physics Letters B |
| Publisher: | World Scientific Publishing Company |
| Additional Information: | Copyright of this article belongs to World Scientific Publishing Company. |
| Department/Centre: | Division of Chemical Sciences > Solid State & Structural Chemistry Unit |
| Date Deposited: | 25 Sep 2007 |
| Last Modified: | 03 Feb 2012 07:16 |
| URI: | http://eprints.iisc.ac.in/id/eprint/11898 |
Actions (login required)
 |
View Item |
