Conformationally Locked Bridged Bicyclic Diselenides: Synthesis, Structure, $Se^{...}O$ Interaction, and Theoretical Studies

Sureshkumar, Devarajulu and Ganesh, Venkataraman and Chandrasekaran, Srinivasan (2007) Conformationally Locked Bridged Bicyclic Diselenides: Synthesis, Structure, $Se^{...}O$ Interaction, and Theoretical Studies. In: Journal of Organic Chemistry, 72 (14). pp. 5313-5319.

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Abstract

A general synthetic methodology has been developed for the synthesis of a conformationally locked, bridged diselena-bicyclo[3.2.1]octane skeleton by regio- and stereospecific tandem nucleophilic ring opening of cis-1,4-aziridino-epoxides with tetraethylammonium tetraselenotungstate $[Et_4N]_2WSe_4$, 1, in a one-pot synthesis. Some correlations have been made on the physicochemical characteristics of the diselenides with a change in the dihedral angles.

Item Type:	Journal Article
Publication:	Journal of Organic Chemistry
Publisher:	American Chemical Society(ACS)
Additional Information:	Copyright of this article bleongs to American Chemical Society(ACS).
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	21 Sep 2007
Last Modified:	19 Sep 2010 04:39
URI:	http://eprints.iisc.ac.in/id/eprint/11861

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