Electronic structures of $RN(PX_2)_2$ $(R=CH_3 or C_6H_5; X=Cl, OCH_3 or OC_6H_5)$ ligands: an ultraviolet photoelectron spectroscopic study

Pradeep, T and Hegde, MS and Balakrishna, MS and Krishnamurthy, SS (1990) Electronic structures of $RN(PX_2)_2$ $(R=CH_3 or C_6H_5; X=Cl, OCH_3 or OC_6H_5)$ ligands: an ultraviolet photoelectron spectroscopic study. In: Journal of Electron Spectroscopy and Related Phenomena, 53 (3). pp. 119-127.

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Abstract

Vapour phase HeI photoelectron spectra of the diphosphazane ligands $RN(PX_2)_2$ $(R=CH_3 or C_6H_5, X=Cl, OCH_3 or OC_6H_5)$ are presented along with the assignments of bands on the basis of molecular orbital calculations. The spectra are in accordance with the structural studies which indicate multiple bonding in the $P-N-P$ segment. The phosphorus lone pair ionization energy appears to follow the a donor ability of the ligands.

Item Type:	Journal Article
Publication:	Journal of Electron Spectroscopy and Related Phenomena
Publisher:	Elsevier Science
Additional Information:	Copyright of this article belongs to Elsevier Science.
Department/Centre:	Division of Chemical Sciences > Solid State & Structural Chemistry Unit Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	02 Jul 2007
Last Modified:	18 Jan 2012 07:02
URI:	http://eprints.iisc.ac.in/id/eprint/11342

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