Elastic properties of binary $AO_3-P_20_5$ and ternary $Na_20-AO_3-P_20_5$ $(A \equiv Mo\hspace{2mm}or\hspace{2mm} W)$ glasses

Muthupari, S and Raghavan, Lakshmi S and Rao, KJ (1996) Elastic properties of binary $AO_3-P_20_5$ and ternary $Na_20-AO_3-P_20_5$ $(A \equiv Mo\hspace{2mm}or\hspace{2mm} W)$ glasses. In: Materials Science and Engineering B, 38 (3). pp. 237-244.

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Abstract

The elastic properties of several compositions of binary $AO_3-P_20_5$ and ternary $Na_20-AO_3-P_20_5$ $(A \equiv Mo\hspace{2mm}or\hspace{2mm}W)$ glasses have been studied using ultrasonic measurements. The trends in the variations in the moduli as a function of composition have been examined. The moduli of the binary glasses exhibit opposite trends. In the ternary glasses the variations in the moduli are consistent with the nature of the structural units formed at various compositions. The variations in the Debye and glass transition temperatures and the average dimensionality of the glasses are also examined on the basis of a structural model of the glasses proposed earlier. The longitudinal modulus, shear modulus and Poisson ratio are found to vary linearly as a function of the covalent bond energy density and also as a function of the product of total cohesive energy density and average dimensionality.

Item Type:	Journal Article
Publication:	Materials Science and Engineering B
Publisher:	Elsevier
Additional Information:	Copyright of this article belongs to Elsevier.
Keywords:	Elastic properties;Molybolophosphate glasses;Tungstophosphate glasses;Ultrasonic measurements
Department/Centre:	Division of Chemical Sciences > Materials Research Centre
Date Deposited:	31 Jan 2007
Last Modified:	19 Sep 2010 04:34
URI:	http://eprints.iisc.ac.in/id/eprint/9622

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