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Cyclic Oligofurans: One-Pot Synthesis of 30\pi and 40\pi Expanded Porphyrinoids

Reddy, Sreedhar J and Mandal, Sukhendu and Anand, Venkataramanarao G (2006) Cyclic Oligofurans: One-Pot Synthesis of 30\pi and 40\pi Expanded Porphyrinoids. In: Organic Letters, 8 (24). 5541 -5543.

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Acid-catalyzed condensation of furan and pentafluorobenzaldehyde yielded conjugated macrocycles with six and eight furan rings. They represent systems similar to annulenes with 30\pi and 40\pi electrons. From their structural analyses, it was found that furan rings in both the molecules were inverted in an alternative fashion and displayed nontwisted conformations.

Item Type: Journal Article
Publication: Organic Letters
Publisher: American Chemical Society
Additional Information: Copyright of this article belongs to American Chemical Society.
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 19 Dec 2006
Last Modified: 19 Sep 2010 04:33
URI: http://eprints.iisc.ac.in/id/eprint/9151

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