Ponnada, S and Kiai, MS and Gorle, DB and Nowduri, A (2021) Improved performance of lithium-sulfur batteries by employing a sulfonated carbon nanoparticle-modified glass fiber separator. In: Nanoscale Advances, 3 (15). pp. 4492-4501.
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Abstract
Some of the most promising alternatives in the energy storage sector are lithium-sulfur batteries, which have a high energy density and theoretical capacity. However, the low electrical conductivity of sulfur and the shuttle effect of polysulfides remain important technical obstacles in the practical use of lithium-sulfur batteries (LSBs). This work employed a glass fiber separator with sulfonated carbon nanoparticles (SCNPs) to reduce the shuttle effect. The negatively charged sulfonic groups in SCNPs might prevent polysulfide migration and anchor lithium polysulfides. By using carbon-based interlayers, this method improves ion conductivity. Furthermore, the equally scattered sulfonic groups serve as active sites, causing sulfur to be distributed consistently and limiting sulfur growth while enhancing active sulfur utilization. After 200 cycles at 1C, the SCNP separator-containing cell showed a specific capacity of 1080 mA h g�1. After 200 cycles, the cell with a CNP separator only showed a specific capacity of 854 mA h g�1, demonstrating that CNPs' polysulfide diffusion suppression was ineffective. The cell with the SCNP separator still showed a high capacity of 901 mA h g�1after 500 cycles, with an average coulombic efficiency of almost 98. © The Royal Society of Chemistry 2021.
| Item Type: | Journal Article |
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| Publication: | Nanoscale Advances |
| Publisher: | Royal Society of Chemistry |
| Additional Information: | The copyright for this article belongs to Authors |
| Keywords: | Carbon; Energy storage; Glass fibers; Lithium batteries; Lithium compounds; Nanoparticles; Polysulfides; Separators, Carbon Nano-Particles; Coulombic efficiency; Diffusion suppression; Electrical conductivity; High energy densities; Negatively charged; Specific capacities; Theoretical capacity, Lithium sulfur batteries |
| Department/Centre: | Division of Chemical Sciences > Materials Research Centre |
| Date Deposited: | 25 Sep 2021 13:34 |
| Last Modified: | 25 Sep 2021 13:34 |
| URI: | http://eprints.iisc.ac.in/id/eprint/69808 |
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