Vaithegi, K and Prasad, KR (2021) Total synthesis of (�)-Cryptofolione. In: Tetrahedron, 79 .
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Official URL: https://dx.doi.org/10.1016/j.tet.2020.131842
Abstract
Enantioselective total synthesis of δ-lactone containing natural product (�)-cryptofolione was accomplished from commercially available benzylidene acetone. Key features of the synthesis include lipase mediated resolution of a β-hydroxy ketone intermediate, DBU mediated isomerization of γ,δ-unsaturated aldehyde to α,β-unsaturated aldehyde, Brown allylation and RCM reactions. © 2020 Elsevier Ltd
Item Type: | Journal Article |
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Publication: | Tetrahedron |
Publisher: | Elsevier Ltd |
Additional Information: | The copyright of this article belongs to Elsevier Ltd |
Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
Date Deposited: | 19 Jan 2021 05:30 |
Last Modified: | 19 Jan 2021 05:30 |
URI: | http://eprints.iisc.ac.in/id/eprint/67679 |
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