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Post-Synthetic Modification of Metal�Organic Frameworks Toward Applications

Mandal, S and Natarajan, S and Mani, P and Pankajakshan, A (2020) Post-Synthetic Modification of Metal�Organic Frameworks Toward Applications. In: Advanced Functional Materials . (In Press)

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Official URL: https://dx.doi.org/10.1002/adfm.202006291

Abstract

Post-synthetic modification (PSM) of metal�organic framework (MOF) compounds is a useful technique for preparing new MOFs that can exhibit or enhance many of the properties of the parent MOFs. PSM can be carried out by a number of approaches such as modifying the linker (ligand) and/or metal node, and adsorption/exchange of guest species. The surface environment of the MOF can be modified to increase structural stability as well as introducing desired properties. There is considerable scope in widening the applications of the MOF with compatible metal or ligand employing the PSM. This review focuses on the recent developments of modified materials through PSM, which augers well for the chemical modification and functionalization of MOFs. In this review, different types of PSM methods are presented in an orderly manner, and the diverse applications of resultant frameworks are described and discussed. © 2020 Wiley-VCH GmbH

Item Type: Journal Article
Publication: Advanced Functional Materials
Publisher: Wiley-VCH Verlag
Additional Information: copyright for this article belongs to Wiley-VCH Verlag
Keywords: Chemical modification; Ligands; Stability, Diverse applications; Functionalizations; Guest species; Modified materials; Postsynthetic modification; Structural stabilities; Surface environments, Metals
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 10 Nov 2020 10:08
Last Modified: 10 Nov 2020 10:08
URI: http://eprints.iisc.ac.in/id/eprint/66974

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