Novel double dealkylation of trialkylphosphite in the presence of an acid: synthesis and characterization of a 16-electron ruthenium complex bearing $P(OH)_2(OMe)$ ligand

Nagaraja, CM and Nethaji, Munirathinam and Jagirdar, Balaji R (2004) Novel double dealkylation of trialkylphosphite in the presence of an acid: synthesis and characterization of a 16-electron ruthenium complex bearing $P(OH)_2(OMe)$ ligand. In: Inorganic Chemistry Communications, 7 (5). pp. 654-656.

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Abstract

A stable, coordinatively unsaturated, 16-electron ruthenium complex bearing $P(OH)_2(OMe)$ has been synthesized and characterized. It reacts with $H_2$ resulting in a highly acidic dihydrogen complex.

Item Type:	Journal Article
Publication:	Inorganic Chemistry Communications
Publisher:	Elsevier
Additional Information:	The copyright belongs to Elsevier.
Keywords:	Acidity;Dihydrogen complex;Hydride complex;Diphosphine;Phosphite;Ruthenium
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	10 May 2006
Last Modified:	19 Sep 2010 04:26
URI:	http://eprints.iisc.ac.in/id/eprint/6661

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