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Self-assembled Pd3L2 cages having flexible tri-imidazole donors

Kumar, Atul and Zangrando, Ennio and Mukherjee, Partha Sarathi (2019) Self-assembled Pd3L2 cages having flexible tri-imidazole donors. In: POLYHEDRON, 172 . pp. 67-73.

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Official URL: https://dx.doi.org/10.1016/j.poly.2019.03.014

Abstract

Four new M3L2 molecular cages (CA1-CA4) have been synthesized in excellent yield via coordination driven self -assembly of flexible tri-imidazole donors based on triazine (L1) and tri-phenyl benzene (L2) core with 90 degrees cis-blocked metal acceptors of Pd(II). Two of them CA1 and CA2 are highly soluble in water. All the cages were characterized by spectroscopic studies and ESI-MS; CA3 and CA4 also by X-ray diffraction. Selective formation of two separate cages CA3 and CA4 was noticed instead of a hetero-ligand cage, when the metal acceptor (dppf)Pd(OTf)(2) was treated with a mixture of ligands L1 and L2.

Item Type: Journal Article
Additional Information: copy right of this article belong to PERGAMON-ELSEVIER SCIENCE LTD
Keywords: Palladium(II); Cage compounds; Self-assembly; Supramolecular chemistry; X-ray structure determination
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Depositing User: Id for Latest eprints
Date Deposited: 19 Dec 2019 09:26
Last Modified: 19 Dec 2019 09:26
URI: http://eprints.iisc.ac.in/id/eprint/64119

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