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Boron-Catalyzed Carbonate Functionality Transfer Reaction

Rao, Santhosh and Ashwathappa, Puneeth Kumar Someswara and Prabhu, Kandikere Ramaiah (2019) Boron-Catalyzed Carbonate Functionality Transfer Reaction. In: ASIAN JOURNAL OF ORGANIC CHEMISTRY, 8 (3). pp. 320-323.

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Official URL: https://dx.doi.org/10.1002/ajoc.201800751


A carbene transfer reaction has been studied to understand the nature of the tris(pentafluorophenyl)borane stabilized donor-acceptor carbene. For this, a carbonate (or dicarbonate) molecule has been employed resulting in an overall carbonate functionality transfer. The results show that the diazo-derived carbenic carbon displays an electrophilic character. This also presents an opportunity to develop future carbene transfer reactions using a multitude of unconventional nucleophiles with the tris(pentafluorophenyl)borane catalyst.

Item Type: Journal Article
Additional Information: copyright for this article belongs to WILEY-V C H VERLAG GMBH
Keywords: boranes; diazo compounds; carbenes; carbonates; nucleophiles
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Depositing User: Id for Latest eprints
Date Deposited: 27 May 2019 07:30
Last Modified: 27 May 2019 07:30
URI: http://eprints.iisc.ac.in/id/eprint/62379

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