ePrints@IIScePrints@IISc Home | About | Browse | Latest Additions | Advanced Search | Contact | Help

The aryne Sommelet-Hauser rearrangement

Roy, T and Gaykar, RN and Bhattacharjee, S and Biju, AT (2019) The aryne Sommelet-Hauser rearrangement. In: Chemical Communications, 55 (20). pp. 3004-3007.

[img] PDF
Che_Com_55-20_3004-3007_2019.pdf - Published Version
Restricted to Registered users only

Download (2MB) | Request a copy
Official URL: https://doi.org/0.1039/c9cc00629j

Abstract

An aryne induced transition-metal-free and mild Sommelet-Hauser rearrangement of tertiary benzylamines for the synthesis of α-aryl amino acid derivatives in moderate to good yields is presented. Unlike the conventional Sommelet-Hauser rearrangement of ammonium salts, the methodology developed herein requires neither harsh conditions nor strong bases. Moreover, a temperature dependent switchable selectivity for the Sommelet-Hauser and Stevens 1,2 rearrangements has been observed. © The Royal Society of Chemistry.

Item Type: Journal Article
Additional Information: Copyright for this article belongs to Royal Society of Chemistry.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Depositing User: Id for Latest eprints
Date Deposited: 09 Apr 2019 05:15
Last Modified: 09 Apr 2019 05:15
URI: http://eprints.iisc.ac.in/id/eprint/62040

Actions (login required)

View Item View Item