Markovnikov-Selective Co(I)-Catalyzed Hydroboration of Vinylarenes and Carbonyl Compounds

Verma, Piyush Kumar and Sethulekshmi, AS and Geetharani, K (2018) Markovnikov-Selective Co(I)-Catalyzed Hydroboration of Vinylarenes and Carbonyl Compounds. In: ORGANIC LETTERS, 20 (24). pp. 7840-7845.

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Abstract

An NHC-supported Co(I) catalyst has been developed for selective Markovnikov hydroboration of vinylarenes under mild reaction conditions. The hydroboration allows highly selective synthesis of a wide range of secondary and tertiary alkyl boronates in excellent yields. Our protocol also enables hydroboration of aldehydes and ketones with diverse functional groups to access the corresponding borate esters.

Item Type:	Journal Article
Publication:	ORGANIC LETTERS
Publisher:	AMER CHEMICAL SOC
Additional Information:	Copyright of this article belongs to AMER CHEMICAL SOC
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	29 Jan 2019 09:03
Last Modified:	29 Jan 2019 09:03
URI:	http://eprints.iisc.ac.in/id/eprint/61541

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