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Reusable Fe2O3-nanoparticle catalysed efficient and selective hydroboration of carbonyl compounds

Shegavi, Mahadev L and Baishya, Ashim and Geetharani, K and Bose, Shubhankar Kumar (2018) Reusable Fe2O3-nanoparticle catalysed efficient and selective hydroboration of carbonyl compounds. In: ORGANIC CHEMISTRY FRONTIERS, 5 (24). pp. 3520-3525.

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Official URL: https://doi.org/10.1039/c8qo00912k

Abstract

The first Fe2O3-nanoparticle catalysed hydroboration of aromatic and aliphatic aldehydes and ketones with HBpin (pin = OCMe2CMe2O) is reported. The reaction proceeds under mild conditions (room temperature) and is moderately sensitive to air. This process is applicable to a broad range of substrates with high functional group compatibility. Moreover, aldehydes are selectively hydroborated over other reducible functional groups, such as ketone, nitrile, hydroxide, alkene, amide, ester, nitro and halide groups.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to ROYAL SOC CHEMISTRY
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Depositing User: Francis Jayakanth
Date Deposited: 10 Feb 2019 09:28
Last Modified: 10 Feb 2019 09:28
URI: http://eprints.iisc.ac.in/id/eprint/61346

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