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Synthesis, structures and magnetic studies of new copper-azides

Mistry, Subhradeep and Natarajan, Srinivasan (2018) Synthesis, structures and magnetic studies of new copper-azides. In: INORGANICA CHIMICA ACTA, 483 . pp. 26-38.

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Official URL: http://dx.doi.org/10.1016/j.ica.2018.08.001


Three new copper(II)-azide compounds, Cu-3(N-3)(6)(Pn)] (I), Cu-6(N-3)(12)(Pn)(2)]center dot CH3OH (II) and Cu-7(N-3)(14)(Pn)(2)] (III), have been prepared employing 1,2-diaminopropane (Pn) as a site blocking amine. Compound I has a one-dimensional (1D) structure, compound II has a two-dimensional (2D) structure and compound III has a three-dimensional (3D) structure. The compounds have Cu-4 units and two metalloligand units in I, Cu-4 and Cu-2 units in II, and Cu-6 clusters and a metalloligand unit in III. The stabilization of different copper clusters was achieved by the subtle variations in the synthetic conditions. The different EO and EE bridgings of the azide promote magnetic exchanges between the copper centers. All the compounds exhibit antiferromagnetic behaviour.

Item Type: Journal Article
Additional Information: Copy right for this article belong to ELSEVIER SCIENCE SA
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 15 Oct 2018 15:24
Last Modified: 15 Oct 2018 15:24
URI: http://eprints.iisc.ac.in/id/eprint/60874

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