Efficient hydroboration of carbonyls by an iron(II) amide catalyst

Baishya, Ashim and Baruah, Swavalina and Geetharani, K (2018) Efficient hydroboration of carbonyls by an iron(II) amide catalyst. In: DALTON TRANSACTIONS, 47 (28). pp. 9231-9236.

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Abstract

An easily prepared iron(II) amide precatalyst enables the selective hydroboration of carbonyls with HBpin (pinacolborane) in the absence of any additive. The reactions proceed with low catalytic loading (1-3 mol%) under mild reaction conditions and display wide functional group compatibility. Aldehydes are selectively hydroborated in the presence of other reducible functional groups, such as ketones, alkenes, nitriles, esters, amides, acids and halides.

Item Type:	Journal Article
Publication:	DALTON TRANSACTIONS
Publisher:	ROYAL SOC CHEMISTRY
Additional Information:	Copy right for this article belong to ROYAL SOC CHEMISTRY
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	05 Oct 2018 15:07
Last Modified:	05 Oct 2018 15:07
URI:	http://eprints.iisc.ac.in/id/eprint/60820

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