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Rh-III-Catalyzed C-H Activation: Mizoroki-Heck-Type Reaction of Maleimides

Bettadapur, Kiran R and Sherikar, Mahadev Sharanappa and Lanke, Veeranjaneyulu and Prabhu, Kandikere Ramaiah (2018) Rh-III-Catalyzed C-H Activation: Mizoroki-Heck-Type Reaction of Maleimides. In: ASIAN JOURNAL OF ORGANIC CHEMISTRY, 7 (7, SI). pp. 1338-1342.

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Official URL: https://dx.doi.org/10.1002/ajoc.201800193


Maleimides are not known to undergo oxidative-Heck reaction because they lack a syn-periplanar beta-hydrogen atom. Herein, we report a C-H activation-based Mizoroki-Heck-type reaction of maleimides using ketone as the directing group. The reaction utilizes a Rh-III-catalyst along with Ag2CO3 as the oxidant to carry out a base-mediated formal beta-hydride elimination.

Item Type: Journal Article
Additional Information: Copyright of this article belong to WILEY-V C H VERLAG GMBH, POSTFACH 101161, 69451 WEINHEIM, GERMANY
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Depositing User: Id for Latest eprints
Date Deposited: 01 Aug 2018 15:22
Last Modified: 01 Aug 2018 15:22
URI: http://eprints.iisc.ac.in/id/eprint/60338

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