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Cobalt(III)-Catalyzed C-H Activation: Azo Directed Selective 1,4-Addition of Ortho C-H Bond to Maleimides

Muniraj, Nachimuthu and Prabhu, Kandikere Ramaiah (2017) Cobalt(III)-Catalyzed C-H Activation: Azo Directed Selective 1,4-Addition of Ortho C-H Bond to Maleimides. In: JOURNAL OF ORGANIC CHEMISTRY, 82 (13). pp. 6913-6921.

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Official URL: http://dx.doi.org/10.1021/acs.joc.7b01094

Abstract

Highly selective azo directed 1,4-addition of an ortiw C-H bond to maleimides has been developed using Co(III); catalyst. This reaction furnishes 3-arylated succinimide derivatives in good yields with excellent selectivity. This protocol exhibits a broad substrate scope and is compatible with symmetrical and unsymmetrical azobenzene derivatives, with maleimides and maleate esters. Preliminary deuterium incorporation studies have been performed to understand the mechanism of the reaction.

Item Type: Journal Article
Additional Information: Copy right for this article belongs to the AMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036 USA
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Depositing User: Id for Latest eprints
Date Deposited: 03 Aug 2017 10:23
Last Modified: 03 Aug 2017 10:23
URI: http://eprints.iisc.ac.in/id/eprint/57573

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