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Pure shift edited ultra high resolution NMR spectrum with complete eradication of axial peaks and unwanted couplings

Mishra, Sandeep Kumar and Suryaprakash, N (2017) Pure shift edited ultra high resolution NMR spectrum with complete eradication of axial peaks and unwanted couplings. In: JOURNAL OF MAGNETIC RESONANCE, 279 . pp. 74-80.

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Official URL: https://doi.org/10.1016/j.jmr.2017.04.014

Abstract

Poor chemical shift dispersion and pairwise interaction among the entire coupled network of spins results in complex one dimensional H-1 NMR spectra, severely hampering the analysis and the accurate determination of (n)J(HH). Available two dimensional selective refocusing based techniques suffer from the evolution of undesirable couplings and intense axial peaks, creating ambiguity in the analysis and the extraction of coupling values. In this work, we report a novel two dimensional experiment for the complete elimination of axial peaks and unwanted couplings, while retaining only the couplings of the selected proton to its partners, with a blend of ultra-high resolution achieved by real time broad band homonuclear decoupling. (C) 2017 Elsevier Inc. All rights reserved.

Item Type: Journal Article
Additional Information: Copy right for this article belongs to the ACADEMIC PRESS INC ELSEVIER SCIENCE, 525 B ST, STE 1900, SAN DIEGO, CA 92101-4495 USA
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Depositing User: Id for Latest eprints
Date Deposited: 21 Jul 2017 10:15
Last Modified: 21 Jul 2017 10:15
URI: http://eprints.iisc.ac.in/id/eprint/57467

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