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Recent Advances in the Synthesis and Reactivity of Vinylcyclopropanes

Ganesh, Venkataraman and Chandrasekaran, Srinivasan (2016) Recent Advances in the Synthesis and Reactivity of Vinylcyclopropanes. In: SYNTHESIS-STUTTGART, 48 (24). pp. 4347-4380.

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Official URL: http://dx.doi.org/10.1055/s-0035-1562530


In this review, we present the recent advances in the synthesis and reactivity of vinylcyclopropanes (VCPs). Various important methodologies involving ylides, carbenoid chemistry, metal-mediated cycloaddition reactions, and allylic cyclization methodologies for the synthesis of VCPs are described. Based on the type of VCPs, their reactivity is dealt under electrophile-, radical-, and nucleophile-mediated reactions. Several examples from transition-metal-mediated ring-opening reactions are discussed. 1 Introduction 2 Synthetic Routes to Vinylcyclopropanes 2.1 Ylide Chemistry 2.2 Transition-Metal-Mediated Synthesis 3 Reactivity of Vinylcyclopropanes 3.1 Electrophile-Mediated Ring-Opening Reactions 3.2 Radical-Mediated Ring-Opening Reactions 3.3 Nucleophile-Mediated Ring-Opening Reactions 3.4 Transition-Metal-Mediated Ring-Opening Reactions 4 Conclusion

Item Type: Journal Article
Additional Information: Copy right for this article belongs to the GEORG THIEME VERLAG KG, RUDIGERSTR 14, D-70469 STUTTGART, GERMANY
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Depositing User: Id for Latest eprints
Date Deposited: 20 Jan 2017 04:17
Last Modified: 20 Jan 2017 04:17
URI: http://eprints.iisc.ac.in/id/eprint/55919

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