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Generation of Hydrogen from Water: A Pd-Catalyzed Reduction of Water Using Diboron Reagent at Ambient Conditions

Ojha, Devi Prasan and Gadde, Karthik and Prabhu, Kandikere Ramaiah (2016) Generation of Hydrogen from Water: A Pd-Catalyzed Reduction of Water Using Diboron Reagent at Ambient Conditions. In: ORGANIC LETTERS, 18 (19). pp. 5062-5065.

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Official URL: http://dx.doi.org/10.1021/acs.orglett.6b02508

Abstract

Production of hydrogen from renewable sources, particularly from water, is an intensive area of research, which-has far-reaching relevance in hydrogen economy. A homogeneous catalytic method is presented for producing clean hydrogen gas from water, in a reaction of water with a diboron compound as the reductant, under ambient reaction conditions. The Pd-catalytic system is stable in water and displays excellent recyclability. Hydroxy analogues such as alcohols are compatible with the Pd/B(2)Pin(2) system and generate hydrogen gas efficiently. The B(2)Pin(2)-H2O system, in the presence of palladium, is an excellent catalytic system for selective hydrogenation of olefins.

Item Type: Journal Article
Additional Information: Copy right for this article belongs to the AMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036 USA
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Depositing User: Id for Latest eprints
Date Deposited: 03 Dec 2016 06:21
Last Modified: 03 Dec 2016 06:21
URI: http://eprints.iisc.ac.in/id/eprint/55269

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