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Synthesis and Structure of Cyclic Trisaccharide with Expanded Glycosidic Linkages

Maiti, Krishnagopal and Jayaraman, Narayanaswamy (2016) Synthesis and Structure of Cyclic Trisaccharide with Expanded Glycosidic Linkages. In: JOURNAL OF ORGANIC CHEMISTRY, 81 (11). pp. 4616-4622.

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Official URL: http://dx.doi.org/10.1021/acs.joc.6b00462

Abstract

A new cyclic trisaccharide is synthesized by cycloglycosylation of a linear trisaccharide, modified with hydroxymethyl moiety at C4 of glucopyranose moiety. The cyclic trisaccharide possesses a rarely observed perfect trigonal symmetry in the P3 space group, in a narrow cone shape, and a brick-wall type arrangement of molecules in the solid state, and exhibits a significantly enhanced binding affinity to 1-aminoadamantane in aqueous solution.

Item Type: Journal Article
Additional Information: Copy right for this article belongs to the AMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036 USA
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Depositing User: Id for Latest eprints
Date Deposited: 05 Jul 2016 06:39
Last Modified: 05 Jul 2016 06:39
URI: http://eprints.iisc.ac.in/id/eprint/54134

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