ePrints@IIScePrints@IISc Home | About | Browse | Latest Additions | Advanced Search | Contact | Help

Enantiospecific synthesis of $tricyclo[5.2.1.0^{4,8}]$decanes via acid catalysed rearrangement of isotwistanes

Srikrishna, A and Satyanarayana, G and Kumar, Ravi P (2006) Enantiospecific synthesis of $tricyclo[5.2.1.0^{4,8}]$decanes via acid catalysed rearrangement of isotwistanes. In: Tetrahedron Letters, 47 (3). pp. 363-366.

[img] PDF
Enantiospecific_synthesis.pdf
Restricted to Registered users only

Download (145kB) | Request a copy

Abstract

An acid catalyzed rearrangement was employed for the enantiospecific conversion of isotwistanol to tricyclo$[5.2.1.0^{4,8}]$decanes, which provided support for the proposed biosynthesis of allopupukeananes from pupukeananes. The strategy has been further extended to the enantiospecific synthesis of a homobrexane.

Item Type: Journal Article
Publication: Tetrahedron Letters
Publisher: Elsevier BV
Additional Information: The copyright belongs to Elsevier BV.
Keywords: Molecular rearrangement;Isotwistanes;Pupukeananes;Allopupukeanane
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 17 Feb 2006
Last Modified: 19 Sep 2010 04:23
URI: http://eprints.iisc.ac.in/id/eprint/5388

Actions (login required)

View Item View Item