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Binding of carboxylatopillar5]arene with alkyl and aryl ammonium salts in aqueous medium

Dasgupta, Suvankar and Chowdhury, Aniket and Mukherjee, Partha Sarathi (2015) Binding of carboxylatopillar5]arene with alkyl and aryl ammonium salts in aqueous medium. In: RSC ADVANCES, 5 (104). pp. 85791-85798.

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Official URL: http://dx.doi.org/10.1039/c5ra13195b

Abstract

The complex formation of alkyl ammonium salts by water-soluble carboxylatopillar5] arene (CP5A) in aqueous medium is reported. p-Xylene diammonium salt and a series of secondary alkyl ammonium salts with various alkyl groups have been prepared and investigated for complex formation. All the ammonium salts exhibit strong host-guest complexation with CP5A under neutral aqueous conditions. H-1 NMR, H-1 DOSY and 2D NOESY NMR experiments have been performed to characterize these inclusion complexes. In this study, the hydrophobic and electrostatic interactions govern the complex formation leading to the formation of pseudorotaxane species. Five pseudo2] rotaxanes and one pseudo3] rotaxane were obtained whose association constant values and stoichiometry were evaluated by an NMR titration method. The results indicate the use of ammonium salts as new complimentary synthons for CP5A in aqueous medium, adding to the repertoire of existing recognition motifs such as paraquat and 1,4-bis(pyridinium) derivatives.

Item Type: Journal Article
Additional Information: Copy right for this article belongs to the ROYAL SOC CHEMISTRY, THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Depositing User: Id for Latest eprints
Date Deposited: 19 Nov 2015 04:57
Last Modified: 19 Nov 2015 04:57
URI: http://eprints.iisc.ac.in/id/eprint/52794

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