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Partial rotation of the isopropyl group in the solid state: single-crystal-to-single-crystal phase transformation in a carvacrol derivative

Pete, Umesh D and Dikundwar, Amol G and Sharma, Vaishali M and Gejji, Shridhar P and Bendre, Ratnamala S and Row, Tayur N Guru (2015) Partial rotation of the isopropyl group in the solid state: single-crystal-to-single-crystal phase transformation in a carvacrol derivative. In: CRYSTENGCOMM, 17 (39). pp. 7482-7485.

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Official URL: http://dx.doi.org/10.1039/c5ce01156f

Abstract

A hitherto unseen rotation of the isopropyl group in the solid state, predicted to be forbidden based on theoretical investigations, is reported. This C-C rotation observed during the temperature dependent single-crystal-to-single-crystal transformation is attributed to the concomitant changes in molecular structure and intermolecular packing.

Item Type: Journal Article
Additional Information: Copy right for this article belongs to the ROYAL SOC CHEMISTRY, THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Depositing User: Id for Latest eprints
Date Deposited: 05 Nov 2015 09:00
Last Modified: 05 Nov 2015 09:00
URI: http://eprints.iisc.ac.in/id/eprint/52701

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