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Organic alloys of room temperature liquids thiophenol and selenophenol

Thomas, Sajesh P and Sathishkumar, R and Row, Guru TN (2015) Organic alloys of room temperature liquids thiophenol and selenophenol. In: CHEMICAL COMMUNICATIONS, 51 (75). pp. 14255-14258.

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Official URL: http://dx.doi.org/10.1039/c5cc03322e

Abstract

The first examples of organic alloys of two room temperature liquids, obtained and characterized via in situ cryo-crystallography, are presented. Thiophenol and selenophenol, which exhibit isostructurality and similar modes of S center dot center dot center dot S and Se center dot center dot center dot Se homo-chalcogen interactions along with weak and rare S-H center dot center dot center dot S and Se-H center dot center dot center dot Se hydrogen bonds, are shown to form solid solutions exhibiting Veggard's law-like trends.

Item Type: Journal Article
Additional Information: Copy right for this article belongs to the ROYAL SOC CHEMISTRY, THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Depositing User: Id for Latest eprints
Date Deposited: 30 Sep 2015 07:10
Last Modified: 30 Sep 2015 07:10
URI: http://eprints.iisc.ac.in/id/eprint/52489

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