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Sulfenyiation of beta-Diketones Using C-H Functionalization Strategy

Varun, Begur Vasanthkumar and Gadde, Karthik and Prabhu, Kandikere Ramaiah (2015) Sulfenyiation of beta-Diketones Using C-H Functionalization Strategy. In: ORGANIC LETTERS, 17 (12). pp. 2944-2947.

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Official URL: http://dx.doi.org/10.1021/acs.orglett.5b01221

Abstract

Sulfenylation of beta-diketones is challenging as beta-diketones undergo deacylation after sulfenylation in the reaction medium. The sulfenylation of beta-diketones without deacylation under metal-free conditions at ambient temperature via a cross dehydrogenative coupling (CDC) strategy is reported. The resultant products can be further manipulated to form alpha,alpha-disubstituted beta-diketones and pyrazoles.

Item Type: Journal Article
Additional Information: Copy right for this article belongs to the AMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036 USA
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Depositing User: Id for Latest eprints
Date Deposited: 31 Jul 2015 13:06
Last Modified: 31 Jul 2015 13:06
URI: http://eprints.iisc.ac.in/id/eprint/51953

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