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4,8,9,10-Tetraphenyl-1,3-diazaadamantan-6-one acetone hemisolvate

Nandhini, Subha M and Krishnakumar, RV and Narasimhamurthy, T and Vijayakumar, V and Sundarvadivelu, M and Natarajan, S (2002) 4,8,9,10-Tetraphenyl-1,3-diazaadamantan-6-one acetone hemisolvate. In: Acta Crystallographica Section E: Structure Reports Online, 58 (11). o1210-o1212.


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In the title compound, $C_{32}H_{28}N_{2}O·0.5C_3H_6O$, the two axial and two equatorial phenyl substituents are essentially planar. There are no hydrogen-bonded interactions between the two independent molecules in the asymmetric unit. The crystal packing is characterized by $C-H{...}O$ interactions. The solvent (acetone) molecule in the crystal structure significantly influences the packing, features of which are distinctly different from those of unsolvated 4,8,9,10-tetraphenyl-1,3-diazaadamantan-6-one and its methoxy- and chloro-substituted analogues.

Item Type: Journal Article
Publication: Acta Crystallographica Section E: Structure Reports Online
Publisher: Blackwell
Additional Information: Copyright for this article belongs to Blackwell Publishing.
Department/Centre: Division of Physical & Mathematical Sciences > Physics
Date Deposited: 01 Feb 2007
Last Modified: 19 Sep 2010 04:23
URI: http://eprints.iisc.ac.in/id/eprint/5175

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