Orotic acid as a useful supramolecular synthon for the fabrication of an OPV based hydrogel: stoichiometry dependent injectable behavior

Bhattacharjee, Subham and Bhattacharya, Santanu (2015) Orotic acid as a useful supramolecular synthon for the fabrication of an OPV based hydrogel: stoichiometry dependent injectable behavior. In: CHEMICAL COMMUNICATIONS, 51 (31). pp. 6765-6768.

PDF che_com-51_31_6765_2015.pdf - Published Version Restricted to Registered users only Download (3MB) | Request a copy

Abstract

A facile hydrogelation of a p-pyridylenevinylene derivative (PV) bearing oxyethylene chains in the presence of orotic acid (OA) occurs via various non-covalent interactions. Depending on the PV: OA molar ratio, the hydrogel shows vesicle to either cluster-type aggregate or fiber transformation. Visual color tuning, stimuli-responsiveness and injectable properties of the hydrogel are also observed.

Item Type:	Journal Article
Publication:	CHEMICAL COMMUNICATIONS
Publisher:	ROYAL SOC CHEMISTRY
Additional Information:	Copy right for this article belongs to the ROYAL SOC CHEMISTRY, THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND
Keywords:	ENERGY-TRANSFER; LOAD-BEARING; PI-SYSTEMS; GEL; VESICLES; STIMULI; AGGREGATION; TRANSITION; MORPHOLOGY; EMISSION
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	06 May 2015 05:34
Last Modified:	06 May 2015 05:34
URI:	http://eprints.iisc.ac.in/id/eprint/51500

Actions (login required)

View Item