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Phase evolutions, growth kinetics and diffusion parameters in the Co-Ni-Ta system

Baheti, Varun A and Santra, Sangeeta and Roy, Soumitra and Perumalsamy, Kiruthika and Prasad, Soma and Ravi, Raju and Paul, Aloke (2015) Phase evolutions, growth kinetics and diffusion parameters in the Co-Ni-Ta system. In: JOURNAL OF ALLOYS AND COMPOUNDS, 622 . pp. 1033-1040.

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Official URL: http://dx.doi.org/ 10.1016/j.jallcom.2014.10.112

Abstract

Diffusion couple experiments are conducted to study phase evolutions in the Co-rich part of the Co-Ni-Ta phase diagram. This helps to examine the available phase diagram and propose a correction on the stability of the Co2Ta phase based on the compositional measurements and X-ray analysis. The growth rate of this phase decreases with an increase in Ni content. The same is reflected on the estimated integrated interdiffusion coefficients of the components in this phase. The possible reasons for this change are discussed based on the discussions of defects, crystal structure and the driving forces for diffusion. Diffusion rate of Co in the Co2Ta phase at the Co-rich composition is higher because of more number of Co-Co bonds present compared to that of Ta-Ta bonds and the presence of Co antisites for the deviation from the stoichiometry. The decrease in the diffusion coefficients because of Ni addition indicates that Ni preferably replaces Co antisites to decrease the diffusion rate. (C) 2014 Elsevier B.V. All rights reserved.

Item Type: Journal Article
Additional Information: Copyright for this article belongs to the ELSEVIER SCIENCE SA, PO BOX 564, 1001 LAUSANNE, SWITZERLAND
Department/Centre: Division of Mechanical Sciences > Materials Engineering (formerly Metallurgy)
Depositing User: Id for Latest eprints
Date Deposited: 12 Jan 2015 10:20
Last Modified: 12 Jan 2015 10:20
URI: http://eprints.iisc.ac.in/id/eprint/50623

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