Simultaneous co-ordination of three cytosine ligands displaying different binding sites around the copper centres

Patil, Yogesh Prakash and Nethaji, Munirathinam (2014) Simultaneous co-ordination of three cytosine ligands displaying different binding sites around the copper centres. In: RSC ADVANCES, 4 (85). pp. 44938-44942.

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Abstract

We report the synthesis and structural characterization of a polymeric ternary copper-cytosine-phenanthroline complex, Cu-4(phen)(3)-(mu(3)-cyt)(2)(mu-OH)(cyt)(OH)Cl-3](n)center dot 16H(2)O, where three cytosine ligands with different binding sites have simultaneously complexed to the four copper metal centres. Interestingly, the complex exhibits two different coordination geometries around the metal centres.

Item Type:	Journal Article
Publication:	RSC ADVANCES
Publisher:	ROYAL SOC CHEMISTRY
Additional Information:	Copy right for this article belongs to the ROYAL SOC CHEMISTRY, THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	20 Nov 2014 04:15
Last Modified:	20 Nov 2014 04:15
URI:	http://eprints.iisc.ac.in/id/eprint/50296

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