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Photocatalytic disassembly of tertiary amine-based dendrimers to monomers and their application to the `catch and release' of a dye in aqueous solution

Sharma, Anindra and Koenig, Burkhard and Jayaraman, Narayanaswamy (2014) Photocatalytic disassembly of tertiary amine-based dendrimers to monomers and their application to the `catch and release' of a dye in aqueous solution. In: NEW JOURNAL OF CHEMISTRY, 38 (8). pp. 3358-3361.

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Official URL: http://dx.doi.org/ 10.1039/c4nj00356j

Abstract

Photocatalytic disassembly of tertiary amine-based poly(propyl ether imine) dendrimers, in the presence of either 9,10-anthraquinone or riboflavin tetraacetate and O-2(g), leads to di- and tripropanolamine monomers. An application is shown by solubilisation of a water-insoluble dye, Sudan I, in aq. dendrimer solution ('catch'), followed by its `release' upon disassembly of the dendrimer.

Item Type: Journal Article
Publication: NEW JOURNAL OF CHEMISTRY
Additional Information: Copy right for this article belongs to the ROYAL SOC CHEMISTRY, THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 27 Aug 2014 09:44
Last Modified: 27 Aug 2014 09:44
URI: http://eprints.iisc.ac.in/id/eprint/49691

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