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Total synthesis of (+)-anamarine

Prasad, Kavirayani R and Kumar, Mothish S (2014) Total synthesis of (+)-anamarine. In: TETRAHEDRON, 70 (30). pp. 4552-4556.

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Official URL: http://dx.doi.org/10.1016/j.tet.2014.04.068

Abstract

An enantiospecific total synthesis of polyhydroxy delta-pyrone natural product (+)-anamarine is accomplished. The main features of the synthesis include the stereoselective reduction of the ketone obtained by the desymmetrization of the bis-dimethyl amide of tartaric acid and further elaboration involving asymmetric Brown's allylation and ring closing metathesis. (C) 2014 Elsevier Ltd. All rights reserved.

Item Type: Journal Article
Additional Information: Copyright for this article belongs to the PERGAMON-ELSEVIER SCIENCE LTD, THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND
Keywords: Anamarine; Polyhydroxy lactone; delta-Pyrone
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Depositing User: Id for Latest eprints
Date Deposited: 11 Aug 2014 04:33
Last Modified: 11 Aug 2014 04:33
URI: http://eprints.iisc.ac.in/id/eprint/49529

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