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Mechanistic studies on the diazo transfer reaction

Pandiakumar, Arun Kumar and Sarma, Siddhartha P and Samuelson, Ashoka G (2014) Mechanistic studies on the diazo transfer reaction. In: TETRAHEDRON LETTERS, 55 (18). pp. 2917-2920.

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Official URL: http://dx.doi.org/10.1016/j.tetlet.2014.03.057

Abstract

The mechanism of the diazo transfer reaction which converts amines to azides has been studied with labeled amino acids and labeled imidazole-l-sulfonyl azides. Retention of amine nitrogen in the amine, and transfer of the two terminal nitrogen atoms of the imidazole-l-sulfonyl azide to the product, were unambiguously established. (C) 2014 Elsevier Ltd. All rights reserved.

Item Type: Journal Article
Additional Information: Copyright for this article belongs to the PERGAMON-ELSEVIER SCIENCE LTD, THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND
Keywords: Imidazole-1-sulfonyl azide.HCl; Labeled L-valine azide; Diazo (-N-2) transfer; S(N)i mechanism; Labeled imidazole-l-sulfonyl azide
Department/Centre: Division of Biological Sciences > Molecular Biophysics Unit
Division of Chemical Sciences > Inorganic & Physical Chemistry
Depositing User: Id for Latest eprints
Date Deposited: 17 Jun 2014 11:02
Last Modified: 17 Jun 2014 11:02
URI: http://eprints.iisc.ac.in/id/eprint/49256

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