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Ring opening of activated cyclopropanes with NIS/NaN3: synthesis of C-1 linked pseudodisaccharides

Haveli, Shrutisagar Dattatraya and Roy, Sudipta and Gautam, Vibha and Parmar, Ketan C and Chandrasekaran, Srinivasan (2013) Ring opening of activated cyclopropanes with NIS/NaN3: synthesis of C-1 linked pseudodisaccharides. In: TETRAHEDRON, 69 (52). pp. 11138-11143.

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Official URL: http://dx.doi.org/10.1016/j.tet.2013.11.005

Abstract

NIS/NaN3 mediated ring opening of various donor-acceptor cyclopropanes has been investigated. The study shows the necessity of the donor oxygen lone pair in such ring opening reactions. This methodology has been utilized in the synthesis of C-1 linked pseudodisaccharides through the use of click chemistry. (C) 2013 Elsevier Ltd. All rights reserved.

Item Type: Journal Article
Additional Information: Copyright for this article belongs to the PERGAMON-ELSEVIER SCIENCE LTD,ENGLAND
Keywords: NIS; Cyclopropane; Donor-acceptor; Click chemistry; Pseudodisaccharides
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Depositing User: Id for Latest eprints
Date Deposited: 13 Feb 2014 12:03
Last Modified: 13 Feb 2014 12:03
URI: http://eprints.iisc.ac.in/id/eprint/48376

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