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Cross-Hetero-Dehydrogenative Coupling Reaction of Phosphites: A Catalytic Metal-Free Phosphorylation of Amines and Alcohols

Dhineshkumar, Jayaraman and Prabhu, Kandikere Ramaiah (2013) Cross-Hetero-Dehydrogenative Coupling Reaction of Phosphites: A Catalytic Metal-Free Phosphorylation of Amines and Alcohols. In: ORGANIC LETTERS, 15 (23). pp. 6062-6065.

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Official URL: http://dx.doi.org/10.1021/ol402956b

Abstract

Phosphorylation of amines, alcohols, and sulfoximines are accomplished using molecular iodine as a catalyst and H2O2 as the sole oxidant under mild reaction conditions. This method provides an easy route for synthesizing a variety of phosphoramidates, phosphorus triesters and sulfoximine-derived phosphoramidates which are of biological importance.

Item Type: Journal Article
Additional Information: copyright for this article belongs to AMER CHEMICAL SOC,USA
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Depositing User: Id for Latest eprints
Date Deposited: 07 Jan 2014 05:38
Last Modified: 07 Jan 2014 05:38
URI: http://eprints.iisc.ac.in/id/eprint/48139

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