ePrints@IIScePrints@IISc Home | About | Browse | Latest Additions | Advanced Search | Contact | Help

Facile synthesis of isochromanones and isoquinolones by AuCl3 catalyzed cascade triggered by an internal nucleophile

Prasad, Kavirayani R and Nagaraju, Chinta (2013) Facile synthesis of isochromanones and isoquinolones by AuCl3 catalyzed cascade triggered by an internal nucleophile. In: Organic Letters, 15 (11). pp. 2778-2781.

[img] PDF
Org_Let_15-11_2778_2013.pdf - Published Version
Restricted to Registered users only

Download (524kB) | Request a copy
[img] PDF
Org_Let_15-11_1_2013.pdf - Published Supplemental Material
Restricted to Registered users only

Download (8MB) | Request a copy
Official URL: http://dx.doi.org/10.1021/ol4011129

Abstract

Synthesis of isochromanones and isoquinolones comprising a quaternary center with high diastereoselectivity was realized via a AuCl3 catalyzed tandem intramolecular exo-dig heterocyclization/enol isomerization/Claisen rearrangement sequence in excellent yields. The reaction is general and amenable for the synthesis of structurally diverse analogues.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to American Chemical Society.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Depositing User: Francis Jayakanth
Date Deposited: 03 Sep 2013 07:09
Last Modified: 03 Sep 2013 07:09
URI: http://eprints.iisc.ac.in/id/eprint/46976

Actions (login required)

View Item View Item