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Enantiospecific total synthesis of indole alkaloids (+)-eburnamonine, (-)-aspidospermidine and (-)-quebrachamine

Nidhiry, John Eugene and Prasad, Kavirayani R (2013) Enantiospecific total synthesis of indole alkaloids (+)-eburnamonine, (-)-aspidospermidine and (-)-quebrachamine. In: Tetrahedron, 69 (26). pp. 5525-5536.

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Official URL: http://dx.doi.org/10.1016/j.tet.2013.04.097

Abstract

An enantiospecific total synthesis of indole alkaloids eburnamonine, aspidospermidine and quebrachamine is described from lactic acid. Synthesis of all three alkaloids is accomplished from a single chiral building block. Johnson-Claisen rearrangement of a chiral allyl alcohol is the main feature for the installation of the required quaternary centre.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier Science.
Keywords: Indole Alkaloids; Total Synthesis; Enantiospecific Synthesis; Claisen Rearrangement
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Depositing User: Francis Jayakanth
Date Deposited: 03 Sep 2013 06:48
Last Modified: 03 Sep 2013 06:48
URI: http://eprints.iisc.ac.in/id/eprint/46964

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