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An Expeditious Enantiospecific Total Synthesis of (-)-Crassalactone C

Prasad, Kavirayani R and Kumar, Mothish S (2013) An Expeditious Enantiospecific Total Synthesis of (-)-Crassalactone C. In: SYNTHESIS-STUTTGART, 45 (6). pp. 785-790.

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Official URL: http://dx.doi.org/10.1055/s-0032-1318303

Abstract

A concise and expeditious approach for the total synthesis of bioactive styryllactone (-)-crassalactone C is presented from tartaric acid. The main features of the synthesis include the desymmetrization of dimethylamide of tartaric acid and the effective use of cinnamoyl ester as a protecting group as well as a reactant in the ring-closing metathesis reaction.

Item Type: Journal Article
Additional Information: Copyright for this article belongs to the GEORG THIEME VERLAG KG, GERMANY.
Keywords: crassalactone C; natural products; stereoselective synthesis; styryllactone
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Depositing User: Francis Jayakanth
Date Deposited: 10 Apr 2013 06:57
Last Modified: 10 Apr 2013 06:57
URI: http://eprints.iisc.ac.in/id/eprint/46317

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