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Enantiospecific Total Synthesis of (-)-Bengamide E

Metri, Prashant K and Schiess, Raphael and Prasad, Kavirayani R (2013) Enantiospecific Total Synthesis of (-)-Bengamide E. In: CHEMISTRY-AN ASIAN JOURNAL, 8 (2). pp. 488-493.

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Official URL: http://dx.doi.org/10.1002/asia.201200999

Abstract

Total synthesis of the polyhydroxy caprolactam amide natural product, bengamide E, is accomplished starting from tartaric acid. Key reactions in the synthesis include desymmetrization of the bis(dimethylamide) unit of tartaric acid, Zn(BH4)2-mediated anti-selective reduction, and a HornerWadsworthEmmons olefination.

Item Type: Journal Article
Additional Information: Copyright for this article belongs to WILEY-V C H VERLAG GMBH, GERMANY
Keywords: anti-cancer compounds;metathesis;natural products;polyhydroxy compounds;total synthesis
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Depositing User: Francis Jayakanth
Date Deposited: 06 Mar 2013 11:09
Last Modified: 06 Mar 2013 11:09
URI: http://eprints.iisc.ac.in/id/eprint/45942

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