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Molecular Marriage through Partner Preferences in Covalent Cage Formation and Cage-to-Cage Transformation

Acharyya, Koushik and Mukherjee, Sandip and Mukherjee, Partha Sarathi (2013) Molecular Marriage through Partner Preferences in Covalent Cage Formation and Cage-to-Cage Transformation. In: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 135 (2). pp. 554-557.

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Official URL: http://dx.doi.org/10.1021/ja310083p

Abstract

Unprecedented self-sorting of three-dimensional purely organic cages driven by dynamic covalent bonds is described. Four different cages were first synthesized by condensation of two triamines and two dialdehydes separately. When a mixture of all the components was allowed to react, only two cages were formed, which suggests a high-fidelity self-recognition. The issue of the preference of one triamine for a particular dialdehyde was further probed by transforming a non-preferred combination to either of the two preferred combinations by reacting it with the appropriate triamine or dialdehyde.

Item Type: Journal Article
Additional Information: Copyright for this article belongs to AMER CHEMICAL SOC, WASHINGTON, USA
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Depositing User: Francis Jayakanth
Date Deposited: 28 Feb 2013 08:30
Last Modified: 28 Feb 2013 08:30
URI: http://eprints.iisc.ac.in/id/eprint/45850

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