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Self-Assembly of an Octanuclear Platinum(II) Tetragonal Prism from a New Pt-4(II) Organometallic Star-Shaped Acceptor and Its Nitroaromatic Sensing Study

Shanmugaraju, Sankarasekaran and Jadhav, Harshal and Patil, Yogesh P and Mukherjee, Partha Sarathi (2012) Self-Assembly of an Octanuclear Platinum(II) Tetragonal Prism from a New Pt-4(II) Organometallic Star-Shaped Acceptor and Its Nitroaromatic Sensing Study. In: INORGANIC CHEMISTRY, 51 (24). pp. 13072-13074.

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Official URL: http://dx.doi.org/10.1021/ic301716y

Abstract

2 + 4] self-assembly of a pyrene-functionalized Pt-8(II) tetragonal prism (2) is achieved using a newly designed star-shaped organometallic acceptor (1) in combination with an amide-based ``clip'' donor (L). The propensity of this prism (2) as a selective sensor for nitroaromatics (2,4-dinitrotoluene, 1,3,5-trinitrotoluene, and picric acid), which are the chemical constituents of many commercial explosives, has been examined.

Item Type: Journal Article
Additional Information: Copyright for this article belongs to AMER CHEMICAL SOC, WASHINGTON,USA
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Depositing User: Francis Jayakanth
Date Deposited: 24 Jan 2013 05:24
Last Modified: 24 Jan 2013 05:25
URI: http://eprints.iisc.ac.in/id/eprint/45663

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