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Synthesis, Spectral Characterization, Crystal Structure and Thermal Behavior of Tert-butyl 2,2-bis(2,4-dinitrophenyl)ethanoate

Kalaivani, D and Malarvizhi, R and Nethaji, M (2012) Synthesis, Spectral Characterization, Crystal Structure and Thermal Behavior of Tert-butyl 2,2-bis(2,4-dinitrophenyl)ethanoate. In: JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 42 (11). pp. 1098-1104.

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Official URL: http://dx.doi.org/10.1007/s10870-012-0363-0

Abstract

Tert-butyl 2,2-bis(2,4-dinitrophenyl)ethanoate was prepared from the ethanolic solution of 1-chloro-2,4-dinitrobenzene, tert-butyl 3-oxobutanoate and triethylamine. Acetyl group in tert-butyl 3-oxobutanoate has cleaved off during the formation of the title molecule. UV-VIS, IR, 1H NMR, 13C NMR, Proton-Proton COSY data and single crystal XRD results support the proposed structure. Flammability test, impact sensitivity test and TG/DTA studies at different heating rates on the synthesized molecule imply that it is an insensitive high energy density material.

Item Type: Journal Article
Additional Information: Copyright for this article belongs to Springer Science+Business Media New York
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Depositing User: Francis Jayakanth
Date Deposited: 31 Dec 2012 05:59
Last Modified: 31 Dec 2012 05:59
URI: http://eprints.iisc.ac.in/id/eprint/45480

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